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燃气轮机热障涂层高温腐蚀研究综述

刘永葆 刘建华 余又红 贺星 刘莉

刘永葆, 刘建华, 余又红, 贺星, 刘莉. 燃气轮机热障涂层高温腐蚀研究综述[J]. 中国舰船研究, 2017, 12(2): 107-115. doi: 10.3969/j.issn.1673-3185.2017.02.014
引用本文: 刘永葆, 刘建华, 余又红, 贺星, 刘莉. 燃气轮机热障涂层高温腐蚀研究综述[J]. 中国舰船研究, 2017, 12(2): 107-115. doi: 10.3969/j.issn.1673-3185.2017.02.014
Yongbao LIU, Jianhua LIU, Youhong YU, Xing HE, Li LIU. Review of hot corrosion of thermal barrier coatings of gas turbine[J]. Chinese Journal of Ship Research, 2017, 12(2): 107-115. doi: 10.3969/j.issn.1673-3185.2017.02.014
Citation: Yongbao LIU, Jianhua LIU, Youhong YU, Xing HE, Li LIU. Review of hot corrosion of thermal barrier coatings of gas turbine[J]. Chinese Journal of Ship Research, 2017, 12(2): 107-115. doi: 10.3969/j.issn.1673-3185.2017.02.014

燃气轮机热障涂层高温腐蚀研究综述

doi: 10.3969/j.issn.1673-3185.2017.02.014
详细信息
    作者简介:

    刘永葆, 男, 1967年生, 博士, 教授。研究方向:燃气轮机监测、控制与故障诊断。E-mail:yongbaoliu@aliyun.com

    通信作者:

    刘建华 (通信作者), 男, 1983年生, 博士生。研究方向:燃气轮机监测、控制与故障诊断。E-mail:ljh363418@sina.cn

  • 中图分类号: U668.3;TK47

Review of hot corrosion of thermal barrier coatings of gas turbine

知识共享许可协议
燃气轮机热障涂层高温腐蚀研究综述刘永葆,等创作,采用知识共享署名4.0国际许可协议进行许可。
  • 摘要:   目的  为了梳理燃气轮机热障涂层服役过程中的高温腐蚀问题,  方法  对燃气轮机热障涂层腐蚀类型和提高抗腐蚀性能的方法分别进行了归纳分析,并展望了提高热障涂层抗腐蚀性能的发展方向。  结果  经归纳分析,燃气轮机热障涂层腐蚀类型主要包括:陶瓷层高温相变、粘结层氧化、盐雾腐蚀、CMAS腐蚀以及燃料杂质腐蚀。提高热障涂层抗腐蚀性能的方法主要有:发展新的抗高温腐蚀涂层材料、进行涂层表面防腐处理、改变涂层系统结构以及提高燃气轮机辅助清洁功能。  结论  未来开发性能优异的新材料仍是提高热障涂层抗腐蚀性能的主要方向,而改进涂层结构设计、材料纳米化对提升热障涂层抗腐蚀性能有很大潜力。随着陶瓷基复合材料的发展,对涂层的高温腐蚀研究将逐步从热障涂层转向环境障涂层(EBC)。
  • 图  1  典型TBC涂层结构系统[2]

    Figure  1.  Typical structure of TBCs[2]

    图  2  复合涂层结构系统[65]

    Figure  2.  Composite structure of TBCs[65]

    图  3  涡轮叶片极限温度的发展[66-67]

    Figure  3.  Tendency of the temperature limitation of the turbine blade[66-67]

  • [1] MILLER R A.History of thermal barrier coatings for gas turbine engines:NASA/TM-2009-215459[R]. Cleveland, Ohio:Glenn Research Center, 2009.
    [2] PADTURE N P, GELL M, JORDAN E H. Thermal barrier coatings for gas-turbine engine applications[J]. Science, 2002, 296(5566):280-284. doi: 10.1126/science.1068609
    [3] 郭洪波, 宫声凯, 徐惠彬.新型高温/超高温热障涂层及制备技术研究进展[J].航空学报, 2014, 35(10):2722-2732.

    GUO H B, GONG S K, XU H B. Research progress on new high/ultra-high temperature thermal barrier coat-ings and processing technologies[J]. Acta Aeronauti-caet Astronautica Sinica, 2014, 35(10):2722-2732(in Chinese).
    [4] STECURA S. Effects of compositional changes on the performance of a thermal barrier coating system:NASA TM-78976[R]. Cleveland, Ohio:Lewis Research Center, 1979.
    [5] KITAZAWA R, TANAKA M, KAGAWA Y, et al. Damage evolution of TBC system under in-phase ther-mo-mechanical tests[J]. Materials Science and Engi-neering:B, 2010, 173(1/2/3):130-134. https://www.researchgate.net/publication/248280590_Damage_Evolution_of_TBC_System_under_in-Phase_Thermo-Mechanical_Tests
    [6] KRÄMER S, YANG J, LEVI C G, et al. Thermochem-ical interaction of thermal barrier coatings with molten CaO-MgO-Al2O3-SiO2(CMAS) deposits[J]. Journal of the American Ceramic Society, 2006, 89(10):3167-3175. doi: 10.1111/jace.2006.89.issue-10
    [7] MILLER R A, GARLICK R G, SMIALEK J L. Phase distributions in plasma-sprayed zirconia-yttria[J]. American Ceramic Society Bulletin, 1983, 62(12):1355-1358. https://www.researchgate.net/publication/4700384_Phase_Distributions_in_Plasma-Sprayed_Zirconia-Yttria
    [8] MILLER R A, SMIALEK J L, GARLICK R G. Phase stability in plasma-sprayed, partially stabilized zirco-nia-yttria[M]//HEUER AH, HOBBSLW. Advances in ceramics, Vol. 3:science and technology of zirconia. Columbus, OH:American Ceramic Society, 1981:241-252.
    [9] EVANS AG, MUMM D R, HUTCHINSON J W, et al. Mechanisms controlling the durability of thermal barri-er coatings[J]. Progress in Materials Science, 2001, 46(5):505-553. doi: 10.1016/S0079-6425(00)00020-7
    [10] JONES R L, GADOMSKI S T. The hot corrosion of CoCrAlY turbine blade coatings by Na2SO4 and vapor-ous NaCl[J]. Journal of the Electrochemical Society, 1977, 124(10):1641-1648. doi: 10.1149/1.2133126
    [11] 项民, 骆军华, 张琦.盐雾腐蚀对热障涂层高温循环氧化性能的影响[J].航空学报, 2006, 27(1):138-141. http://www.cnki.com.cn/Article/CJFDTOTAL-HKXB200601027.htm

    XIANG M, LUO J H, ZHANG Q. Influence of salt spray corrosion on high-temperature cyclic oxidation behavior of thermal barrier coatings[J]. Acta Aero-nauticaet Astronautica Sinica, 2006, 27(1):138-141(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-HKXB200601027.htm
    [12] EVANS A G, FLECK N A, FAULHABER S, et al. Scalinglaws governing the erosion andimpact resis-tance of thermal barrier coatings[J]. Wear, 2006, 260(7/8):886-894. https://www.researchgate.net/publication/222546283_Scaling_Laws_Governing_the_Erosion_and_Impact_Resistance_of_Thermal_Barrier_Coatings
    [13] DREXLER J M, SHINODA K, ORTIZ AL, et al. Air-plasma-sprayed thermal barrier coatings that are resistant to high-temperature attack by glassy deposits[J]. Acta Materialia, 2010, 58(20):6835-6844. doi: 10.1016/j.actamat.2010.09.013
    [14] STOTT F H, DE WET D J, TAYLOR R. Degradation of thermal-barrier coatings at very high temperatures[J]. MRS Bulletin, 1994, 19(10):46-49. doi: 10.1557/S0883769400048223
    [15] PENG H, WANG L, GUO L, et al. Degradation of EB-PVD thermal barrier coatings caused by CMAS deposits[J]. Progress in Natural Science:Materials International, 2012, 22(5):461-467. doi: 10.1016/j.pnsc.2012.06.007
    [16] KRAUSE A R, GARCES H F, DWIVEDI G, et al. Calcia-magnesia-alumino-silicate (CMAS)-in-duced degradation and failure of air plasma sprayed yttria-stabilized zirconia thermal barrier coatings[J]. Acta Materialia, 2016, 105:355-366. doi: 10.1016/j.actamat.2015.12.044
    [17] VIDAL-SETIF M H, CHELLAH N, RIO C, et al. Calcium-magnesium-alumino-silicate (CMAS) deg-radation of EB-PVD thermal barrier coatings:charac-terization of CMAS damage on ex-service high pres-sure blade TBCs[J]. Surface and Coatings Technolo-gy, 2012, 208:39-45. doi: 10.1016/j.surfcoat.2012.07.074
    [18] 张小锋, 周克崧, 宋进兵, 等.等离子喷涂-物理气相沉积7YSZ热障涂层沉积机理及其CMAS腐蚀失效机制[J].无机材料学报, 2015, 30(3):287-293. doi: 10.15541/jim20140397

    ZHANG X F, ZHOU K S, SONG J B, et al. Deposi-tion and CMAS corrosion mechanism of 7YSZ thermal barriercoatings prepared by plasma spray-physical va-por deposition[J]. Journal of Inorganic Materials, 2015, 30(3):287-293(in Chinese). doi: 10.15541/jim20140397
    [19] JONES R L. Some aspects of the hot corrosion of ther-mal barrier coatings[J]. Journal of Thermal Spray Technology, 1997, 6(1):77-84. doi: 10.1007/BF02646315
    [20] BRATTON R J, LAU S K, ANDERSSON C A, et al. Studies of thermal barrier coatings for heat engines[C]//Proceedings of the 2nd Conference on Advanced Materials for Alternative-Fuel-Capable Heat En-gines. Palo Alto, America:Electric Power Research Institute, 1982:6-101.
    [21] KVEMES I, SOLBERG J K, LILLERUD K P. Ceram-ic coatings on diesel engine components[C]//Proceed-ings of the 1st Conference onAdvanced Materials for Alternative Fuel Capable Directly Fired Heat Engines. US:U. S. Dept. of Energy, CONF-790749, 1979:233-257.
    [22] HAMILTON J C, NAGELBERG A S. In Situ Raman spectroscopic study of yttria-stabilized zirconia attack by molten sodium vanadate[J]. Journal of the Ameri-can Ceramic Society, 1984, 67(10):686-690. doi: 10.1111/jace.1984.67.issue-10
    [23] BARKALOW R H, PETTIT E S. Mechanisms of hot corrosion attack of ceramic coating materials[C]//Pro-ceedings of the 1st Conference onAdvanced Materials for Alternative Fuel Capable Directly Fired Heat En-gines, CONF-790749. US:U.S. Dept. of Energy, 1979:704-714.
    [24] SINGHAL S C, BRATTON R J. Stability of a ZrO2(Y2O3) thermal barrier coating in turbine fuel with contaminants[J]. Journal of Engineering for Power, 1980, 102(4):770-775. doi: 10.1115/1.3230339
    [25] JONES R L. The development of hot-corrosion-resis-tant zirconia thermal barrier coatings[J]. Materials at High Temperatures, 1991, 9(4):228-236. doi: 10.1080/09603409.1991.11689664
    [26] MCKEE D W, LUTHRA K L, SIEMERS P, et al. Resistance of thermal barrier ceramic coatings to hot salt corrosion[C]//Proceedings of the 1st Conferen-ceon Advanced Materials for Alternative Fuel Capa-ble Directly Fired Heat Engines. US:U.S. Dept. of En-ergy, 1979:258-269.
    [27] VASSEN R, CAO X Q, TIETZ F, et al. Zirconates as new materials for thermal barrier coatings[J]. Jour-nal of the American Ceramic Society, 1999, 83(8):2023-2028. http://www.wenkuxiazai.com/doc/8f812b3031126edb6f1a108e-2.html
    [28] YUGESWARAN S, KOBAYASHI A, ANANTHA-PADMANABHAN P V. Hot corrosion behaviors of gas tunnel type plasma sprayed La2Zr2O7 thermal barri-er coatings[J]. Journal of the European Ceramic Soci-ety, 2012, 32(4):823-834. doi: 10.1016/j.jeurceramsoc.2011.10.049
    [29] YUGESWARAN S, KOBAYASHI A, ANANTHA-PADMANABHAN P V. Initial phase hot corrosion mechanism of gas tunnel type plasma sprayed thermal barrier coatings[J]. Materials Science and Engineer-ing:B, 2012, 177(7):536-542. doi: 10.1016/j.mseb.2011.12.037
    [30] XIE X Y, GUO H B, GONG S K, et al. Hot corro-sion behavior of double-ceramic-laye LaTi2Al9O19/YSZ thermal barrier coatings[J]. Chinese Journal of Aeronautics, 2012, 25(1):137-142. doi: 10.1016/S1000-9361(11)60372-5
    [31] HABIBI M H, WANG L, LIANG J D, et al. An in-vestigation on hot corrosion behavior of YSZ-Ta2O5 in Na2SO4+ V2O5 salt at 1100℃[J]. Corrosion Science, 2013, 75:409-414. doi: 10.1016/j.corsci.2013.06.025
    [32] HABIBI M H, YANG S Z, GUO S M. Phase stability and hot corrosion behavior of ZrO2-Ta2O5 compound in Na2SO4-V2O5 mixtures at elevated temperatures[J]. Ceramics International, 2014, 40(3):4077-4083. doi: 10.1016/j.ceramint.2013.08.062
    [33] CHEN X L, ZHAO Y, GU L J, et al. Hot corrosion behaviour of plasma sprayed YSZ/LaMgAl11O19 com-posite coatings in molten sulfate-vanadate salt[J]. Corrosion Science, 2011, 53(6):2335-2343. doi: 10.1016/j.corsci.2011.03.019
    [34] JONES R L. Scandia-stabilized zirconia for resis-tance to molten vanadate-sulfate corrosion[J]. Sur-face and Coatings Technology, 1989, 39/40:89-96. doi: 10.1016/0257-8972(89)90044-3
    [35] STECURA S. New ZrO2-Yb2O3 plasma-sprayed coat-ings for thermal barrier applications[J]. Thin Solid Films, 1987, 150(1):15-40. doi: 10.1016/0040-6090(87)90305-1
    [36] JONES R L, MESS D. India as a hot corrosion-resis-tant stabilizer for zirconia[J]. Journal of the Ameri-can Ceramic Society, 1992, 75(7):1818-1821. doi: 10.1111/jace.1992.75.issue-7
    [37] PARKA S Y, KIM J H, KIM M C, et al. Microscopic observation of degradation behavior in yttriaand ceria stabilized zirconia thermal barrier coatings under hot corrosion[J]. Surface and Coatings Technology, 2005, 190(2/3):357-365. https://www.researchgate.net/publication/248237328_Microscopic_Observation_of_Degradation_Behavior_in_Yttria_and_Ceria_Stabilized_Zirconia_Thermal_Barrier_Coatings_Under_Hot_Corrosion
    [38] KHOR K A, YANG J. Plasma sprayed ZrO2-Sm2O3 coatings:lattice parameters, tetragonality (c/a) and transformability of tetragonal zirconia phase in plas-ma-sprayed ZrO2-Er2O3 coatings[J]. Journal of Ma-terials Science Letters, 1997, 16(12):1002-1004. doi: 10.1023/A:1018597802063
    [39] SURESH A, MAYO M J, POTER W D. Thermody-namics of the tetragonal-to-monoclinic phase trans-formation in fine and nanocrystallineyttria-stabilized zirconia powders[J]. Journal of Materials Research, 2003, 18(12):2912-2921. doi: 10.1557/JMR.2003.0406
    [40] GARVIE R C, GOSS M F. Intrinsic size dependence of the phase transformation temperature in zirconia microcrystals[J]. Journal of Materials Science, 1986, 21(4):1253-1257. doi: 10.1007/BF00553259
    [41] GHASEMI R, SHOJA-RAZAVI R, MOZAFARINIA R, et al. Comparison of microstructure and mechani-cal properties of plasma-sprayed nanostructured and conventional yttria stabilized zirconia thermal barrier coatings[J]. Ceramics International, 2013, 39(8):8805-8813. doi: 10.1016/j.ceramint.2013.04.068
    [42] JAMALI H, MOZAFARINIA R, RAZAVI R S, et al. Fabrication and evaluation of plasma-sprayed nano-structured and conventional YSZ thermal barrier coat-ings[J]. Current Nanoscience, 2012, 8(3):402-409. doi: 10.2174/157341312800620250
    [43] LIMA R S, MARPLE B R. Toward highly sinter-ing-resistant nanostructured ZrO2-7 wt.% Y2O3 coat-ings for TBC applications by employing differential sintering[J]. Journal of Thermal Spray Technology, 2008, 17(5/6):846-852.
    [44] LIMA R S, MARPLE B R. Nanostructured YSZ ther-mal barrier coatings engineered to counteract sinter-ing effects[J]. Materials Science and Engineering:A, 2008, 485(1/2):182-193.
    [45] WU J, GUO H B, ZHOU L, et al. Microstructure and thermal properties of plasma sprayed thermal bar-rier coatings from nanostructured YSZ[J]. Journal of Thermal Spray Technology, 2010, 19(6):1186-1194. doi: 10.1007/s11666-010-9535-7
    [46] JAMALI H, MOZAFARINIA R, SHOJA-RAZAVI R, et al. Comparison of hot corrosion behaviors of plasma-sprayed nanostructured and conventional YSZ thermal barrier coatings exposure to molten vana-dium pentoxide and sodium sulfate[J]. Journal of the European Ceramic Society, 2014, 34(2):485-492. doi: 10.1016/j.jeurceramsoc.2013.08.006
    [47] TSAI P C, HSU C S. High temperature corrosion re-sistance and microstructural evaluation of la-ser-glazed plasma-sprayed zirconia/MCrAlY thermal barrier coatings[J]. Surface and Coatings Technolo-gy, 2004, 183(1):29-34. doi: 10.1016/j.surfcoat.2003.08.090
    [48] TSAI P C, LEE J H, HSU C S. Hot corrosion behav-ior of laser-glazed plasma-sprayed yttria-stabilized zirconia thermal barrier coatings in the presence of V2O5[J]. Surface and Coatings Technology, 2007, 201(9/10/11):5143-5147.
    [49] BATISTA C, PORTINHA A, RIBEIRO R M, et al. Evaluation of laser-glazed plasma-sprayed thermal barrier coatings under high temperature exposure to molten salts[J]. Surface and Coatings Technology, 2006, 200(24):6783-6791. doi: 10.1016/j.surfcoat.2005.10.011
    [50] YAN S, SHANG Y J, XU X F, et al. Improving an-ti-corrosion property of thermal barrier coatings by in-tense pulsed ion beam irradiation[J]. Nuclear Instru-ments and Methods in Physics Research Section B, 2012, 272:450-453. doi: 10.1016/j.nimb.2011.01.121
    [51] CHEN Z, WU N Q, SINGH J, et al. Effect of Al2O3 overlay on hot-corrosion behavior of yttria-stabilized zirconia coating in molten sulfate-vanadate salt[J]. Thin Solid Films, 2003, 443(1/2):46-52.
    [52] AFRASIABI A, SAREMI M, KOBAYASHI A. A comparative study on hot corrosion resistance of three types of thermal barrier coatings:YSZ, YSZ + Al2O3 and YSZ/Al2O3[J]. Materials Science and Engineer-ing:A, 2008, 478(1/2):264-269.
    [53] ZHONG X H, WANG Y M, XU Z H, et al. Hot-cor-rosion behaviors of overlay-clad yttria-stabilized zir-conia coatings in contact with vanadate-sulfate salts[J]. Journal of the European Ceramic Society, 2010, 30(6):1401-1408. doi: 10.1016/j.jeurceramsoc.2009.10.017
    [54] NEJATI M, RAHIMIPOUR M R, MOBASHER-POUR I. Evaluation of hot corrosion behavior of CSZ, CSZ/microAl2O3 and CSZ/nanoAl2O3 plasma sprayed thermal barrier coatings[Z]. Ceramics International, 2014, 40(3):4579-4590. doi: 10.1016/j.ceramint.2013.08.135
    [55] KNUUTTILA J, SORSA P, MÄNTYLÄ T, et al. Sealing of thermal spray coatings by impregnation[J]. Journal of Thermal Spray Technology, 1999, 8(2):249-257. doi: 10.1007/s11666-999-0002-2
    [56] TROCZYNSKI T, YANG Q, JOHN G. Post-deposi-tion treatment of zirconia thermal barrier coatings us-ing Sol-Gel alumina[J]. Journal of Thermal Spray Technology, 1999, 8(2):229-234. doi: 10.1361/105996399770350458
    [57] 曹雪强.热障涂层材料[M].北京:科学出版社, 2007:11.

    CAO X Q. Thermal barrier coating materials[M]. Bei-jing:Science Press, 2007:11(in Chinese).
    [58] MÜLLER J, NEUSCHÜTZ D. Efficiency of α-alumi-na as diffusion barrier between bond coat and bulk material of gas turbine blades[J]. Vacuum, 2003, 71(1/2):247-251.
    [59] KURANISHI T, HABAZAKI H, KONNO H. Oxida-tion-resistant multilayer coatings using an anodic alu-mina layer as a diffusion barrier on γ-TiAl substrates[J]. Surface and Coatings Technology, 2005, 200(7):2438-2444. doi: 10.1016/j.surfcoat.2004.08.211
    [60] 张晓囡, 张华芳, 李庆芬, 等.热障涂层界面扩散阻挡层研究进展[J].材料导报, 2008, 22(4):14-17. http://www.cnki.com.cn/Article/CJFDTOTAL-CLDB200804004.htm

    ZHANG X N, ZHANG H F, LI Q F, et al. Research development of interface diffusion barriers in thermal barrier coatings[J]. Materials Review, 2008, 22(4):14-17(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-CLDB200804004.htm
    [61] 蔡妍, 易军, 陆峰, 等.热障涂层金属元素扩散阻挡层研究进展[J].材料工程, 2011(9):92-96. http://www.cnki.com.cn/Article/CJFDTOTAL-CLGC201109017.htm

    CAI Y, YI J, LU F, et al. Development in research on metal diffusion barrier of TBCs[J]. Journal of Ma-terials Engineering, 2011(9):92-96(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-CLGC201109017.htm
    [62] 蔡妍, 李建平, 陆峰, 等.电弧离子镀TiC扩散障结构及抗高温氧化性能研究[J].真空, 2010, 47(5):5-8. http://www.cnki.com.cn/Article/CJFDTOTAL-ZKZK201005003.htm

    CAI Y, LI J P, LU F, et al. Structure and antioxida-tion behavior of TiC diffusion barrier prepared by arc ion plating[J]. Vacuum, 2010, 47(5):5-8(in Chi-nese). http://www.cnki.com.cn/Article/CJFDTOTAL-ZKZK201005003.htm
    [63] SU Y F. Protective control of the metal-ceramic inter-face behavior of thermal barrier coatings using an arti-ficial α-Al2O3layer[D]. USA:Stevens Institute of Technology, 2003.
    [64] TAKAHASHI M, ITOH Y, MIYAZAKIA M. Ther-mal barrier coatings design for gas turbine[C]//OHM-ORI A. Proceedings of 14th International Thermal Spraying. Kobe Japan:High Temperature Society of Japan, 1995:83-88.
    [65] KAWASAKI A, WATANABE R. Cyclic thermal frac-ture behavior and spallation life of PSZ/NiCrAlY func-tionally graded thermal barrier coatings[J]. Materials Science Forum, 1999, 308/311:402-409. doi: 10.4028/www.scientific.net/MSF.308-311
    [66] ZHU D M, MILLER R A. Thermal and environmental barrier coatings for advanced propulsion engine sys-tems:NASA/TM-2004-213129[R]. Cleveland, Ohio:Lewis Research Center, 2004.
    [67] 周益春, 刘奇星, 杨丽, 等.热障涂层的破坏机理与寿命预测[J].固体力学学报, 2010, 31(5):504-531. http://www.cnki.com.cn/Article/CJFDTOTAL-GTLX201005010.htm

    ZHOU Y C, LIU Q X, YANG L, et al. Failure mech-anisms and life prediction of thermal barrier coatings[J]. Chinese Journal of Solid Mechanics, 2010, 31(5):504-531(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-GTLX201005010.htm
    [68] RAMASAMY S, TEWARIS N, LEEK N, et al. EBC development for hot-pressed Y2O3/Al2O3 doped silicon nitride ceramics[J]. Materials Science and Engineer-ing:A, 2010, 527(21/22):5492-5498.
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  • 收稿日期:  2016-07-25
  • 网络出版日期:  2017-03-13
  • 刊出日期:  2017-04-01

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